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Beilstein J. Org. Chem. 2015, 11, 617–621, doi:10.3762/bjoc.11.69
Graphical Abstract
Figure 1: Terminal sialic acids are typically α-(2,3) or α-(2,6) linked to galactose (Gal) such as in the tum...
Scheme 1: (a) FmocCl, py, CH2Cl2, rt, 4 h, 77%, (b) 2-chloroacetyl chloride, py, CH2Cl2, 0 °C to rt, 3 h, 88%...
Scheme 2: Automated synthesis of oligosaccharides with α(2,3)-, α(2,6)-sialic acid linkages. Glycosylations: ...